Temperature compensated magnetic field apparatus for nmr measurements

ABSTRACT

An apparatus is disclosed for generating a magnetic field of high field strength, spatial uniformity and minimal drift of magnetic field intensity over a temperature range of about 0° C. to 175° C. This apparatus may be used in a standard modular logging tool for direct downhole NMR measurements of various parameters of fluid samples of geologic formations near the walls of a borehole. In one embodiment, the apparatus is composed of two tubular permanent magnets made of different magnetic materials with different magnetic temperature coefficients to provide temperature compensation. The apparatus preferably also utilizes a pressure barrel that surrounds the magnets and provides a return path for magnetic flux lines, thereby increasing flux density within the measurement volume.

FIELD OF THE INVENTION

[0001] The present invention relates to borehole measurements and moreparticularly to the generation of temperature-compensated magneticfields suitable for performing downhole measurements of fluids usingnuclear magnetic resonance (NMR) techniques.

BACKGROUND OF THE INVENTION

[0002] Performing measurements on fluid samples is desirable in many oilindustry applications. In the prior art such measurements are typicallymade by bringing samples to the surface using sealed containers, andsending the samples for laboratory measurements. A number of technicaland practical limitations are associated with this approach.

[0003] The main concern usually is that the sample(s) taken to thesurface may not be representative of the downhole geologic formation dueto the fact that only limited sample material from a limited number ofdownhole locations can be extracted and taken to the surface. Thus,taking samples to the surface is impractical if it is desired to measurethe fluid on a dense grid of sample points. Therefore, by necessity themeasurements will only provide an incomplete picture of the downholeconditions. In addition, these samples frequently contain highlyflammable hydrocarbon mixtures under pressure. Depressurizing thecontainers frequently leads to the loss of the gas content. Handling ofsuch test samples can be hazardous and costly. It is therefore apparentthat there is a need for direct downhole fluid testing that wouldovercome these and other problems associated with prior art solutions.

[0004] Various methods exist for performing downhole measurements ofpetrophysical parameters of a geologic formation. Nuclear magneticresonance (NMR) logging is among the most important methods that havebeen developed for a rapid determination of such parameters, includingformation porosity, composition of the formation fluid, the quantity ofmovable fluid, permeability and others.

[0005] Some of the main formation parameters measured using NMRtechniques include the parameter T₁ (known as the spin-latticerelaxation time), which corresponds to the rate at which equilibrium isestablished in bulk magnetization in the formation upon provision of astatic magnetic field. Another related and frequently used NMR loggingparameter is the spin-spin relaxation time constant T₂ (also known astransverse relaxation time), which is an expression of the relaxationdue to non-homogeneities in the local magnetic field over the sensingvolume of the logging tool. Both relaxation times provide indirectinformation about the formation porosity, the composition and quantityof the formation fluid, and others.

[0006] Another measurement parameter used in NMR well logging is theformation diffusion, which generally, refers to the motion of atoms in agaseous or liquid state due to their thermal energy. It is well knownthat a correct interpretation of the NMR measurement parameters T₁, T₂and diffusivity may provide valuable information relating to the typesof fluids involved, the structure of the formation and other welllogging parameters of interest. The accuracy of the measurements, andthus the validity of the derived information, depends on a number offactors, including the ability of the measurement tool to provideconsistent measurement results over a wide range of practicalconditions, such as the operating temperature.

[0007] NMR measurements of geologic formations may be done using, forexample, the centralized MRIL® tool made by NUMAR, a Halliburtoncompany, and the side-wall CMR tool made by Schlumberger. The MRIL® toolis described, for example, in U.S. Pat. No. 4,710,713 to Taicher et al.and in various other publications including: “Spin Echo MagneticResonance Logging: Porosity and Free Fluid Index Determination,” byMiller, Paltiel, Millen, Granot and Bouton, SPE 20561, 65th AnnualTechnical Conference of the SPE, New Orleans, La., September 23-26,1990; “Improved Log Quality With a Dual-Frequency Pulsed NMR Tool,” byChandler, Drack, Miller and Prammer, SPE 28365, 69th Annual TechnicalConference of the SPE, New Orleans, La., September 25-28, 1994). Detailsof the structure of the MRIL® tool and the measurement techniques ituses are also discussed in U.S. Pat. Nos. 4,717,876; 4,717,877;4,717,878; 5,212,447; 5,280,243; 5,309,098; 5,412,320; 5,517,115;5,557,200; 5,696,448; 5,936,405; 6,005,389; 6,023,164; 6,051,973;6,107,796 and 6,111,408, all of which are commonly owned by the assigneeof the present application. The Schlumberger CMR tool is described, forexample, in U.S. Pat. Nos. 5,055,787 and 5,055,788 to Kleinberg et al.and further in “Novel NMR Apparatus for Investigating an ExternalSample,” by Kleinberg, Sezginer and Griffin, J. Magn. Reson. 97,466-485, 1992. The content of the above patents and publications ishereby expressly incorporated by reference for background.

[0008] Wireline logging of boreholes performed using the NMR toolsdescribed above or other techniques known in the art provides valuableinformation concerning the petrophysical properties of the formationand, in particular, regarding the fluid composition of the formation.However, additional fluid parameter information can be critical for theinterpretation of the wireline NMR measurements. For example, it isoften desirable to distinguish between water, connate oil, drilling mudfiltrates and gas based on the differences in T₁, T₂ and diffusivity.The true values for connate oil and the drilling mud filtrates underreservoir conditions are often unknown and must be approximated fromlaboratory measurements done under different conditions. Therefore, forincreased accuracy, it is desirable to perform real-time downhole NMRdetermination of the T₁, T₂ and diffusivity parameters of boreholefluids to enhance the quality and reliability of the formationevaluation obtained using the standard measurements.

[0009] Direct downhole measurements of certain fluid properties areknown in the art. Several commercially available tools may be used tothis end. Examples include the RDT tool manufactured by Halliburton, theReservoir Characterization Instrument (RCI) from Western Atlas, and theModular Formation Dynamics Tester (MDT) made by Schlumberger. Thesetester tools have modular design that allows them to be reconfigured atthe well site. Typically, these tools provide pressure-volumemeasurements, which may be used to differentiate liquids from gases, andwhich are also capable of providing temperature, resistivity and othermechanical or electrical measurements. However, none of these tools ispresently capable of providing NMR measurements, such hydrogen density,self diffusivity, or relaxation times.

[0010] A tester capable of performing direct downhole NMR measurementsthat can be used to enhance the quality and reliability of formationevaluation and that can provide a modular NMR downhole tester as anadd-on to existing testing equipment to minimize the cost of extrameasurement is disclosed in U.S. Pat. No. 6,111,408, entitled “NuclearMagnetic Resonance Sensing Apparatus and Techniques For DownholeMeasurements” by the present inventors.

[0011] The ability of such a tester to perform rapid and accurate NMRmeasurements is critically dependent on the ability to produce anintense and uniform magnetic field in the test vessel containing thefluids of interest. A downhole tester, such as that disclosed in U.S.Pat. No. 6,111,408, is exposed to extreme changes of temperature and themagnetic field generated in the test vessel of such a downhole testermust show little drift with temperature and should not be influenced byexternal fields and materials.

[0012] Therefore, there is a need for an apparatus for the generation ofa magnetic field in a test vessel of a downhole tester, which is able togenerate a static magnetic field of high field strength, spatialuniformity and minimal drift over a wide temperature range suitable forpractical applications, e.g., 0° C. to 175 ° C. In addition, there is aneed for an apparatus, the magnetic field of which is largely confinedto an interior volume of the test vessel, so that the influence ofexternal fields and materials is minimized or eliminated.

SUMMARY OF THE INVENTION

[0013] Described herein is an apparatus for the generation of aspatially uniform and temperature compensated magnetic field, within agiven volume for use with nuclear magnetic resonance (NMR) techniques.In particular, an apparatus for generating a magnetic field suitable fora modular NMR tester capable of making direct downhole NMR measurementsof various parameters of fluid samples of geologic formations near thewalls of a borehole is provided. The modular tester is preferablyincorporated as an add-on part to a standard commercial downholeformation tester.

[0014] In operation, test fluids located proximate to the borehole areintroduced into a test chamber of the tester. In a preferred embodiment,the tester comprises a vessel made of a non-conductive material and asurrounding permanent magnet that creates a uniform, static,temperature-compensated magnetic field within the test chamber. In apreferred embodiment, a radio frequency (RF) coil is embedded in thewalls of the vessel and is used to induce an excitation field with adirection perpendicular to the static magnetic field. NMR signals fromthe excited nuclei in the fluids are detected to obtain data fordirectly estimating a number of fluid parameters, or to assist in theinterpretation of wireline MRIL measurements.

[0015] More specifically, in a preferred embodiment, an apparatus isprovided for generating a uniform, temperature-compensated magneticfield suitable for use in a downhole NMR tester such as that disclosedin U.S. Pat. No. 6,111,408 to the present inventors, which is herebyincorporated by reference for all purposes. According to one embodiment,the apparatus comprises: a first magnet having longitudinal axis,magnetized in a direction that is perpendicular to the longitudinalaxis; and at least a second magnet also in the form of a tube that isco-axial with and is within the first magnet tube. The second magnet isalso magnetized in a direction that is perpendicular to its longitudinalaxis and at some angle, preferably 0° or 180°, to the magnetizationdirection of the first magnet.

[0016] In one aspect of the invention, the first and second magnets arecomposed of materials having different magnetic temperature coefficientsand therefore the combined magnetic field within the internal volume ofthe magnets will vary less with temperature than the field within acomparable magnet assembly having just one type of magnetic material.

[0017] In another aspect of the invention, the apparatus furthercomprises a tubular pressure barrel co-axial with and containing boththe first and second magnets. In a preferred embodiment, the pressurebarrel is made of metal with a high relative magnetic permeability, suchas soft-iron or low-carbon steel, and thus provides a low resistancepath for magnetic field lines outside the magnets. This return path forthe magnetic flux increases the magnetic flux density within theinterior volume of the magnets.

[0018] In addition, in a preferred embodiment of the apparatus, thecross-sectional area of the first magnet and the cross-sectional area ofthe second magnet are selected in a ratio proportional to the ratio ofthe inverse of their respective temperature coefficients to enhance thetemperature compensation effect. Alternatively or in addition, thedegrees of magnetization of the two magnets may be selected inaccordance with their respective temperature coefficients.

[0019] In one embodiment, the two magnets have different magnetictemperature coefficients with the same sign, and the angle between thedirection of magnetization of the first magnet and that of the secondmagnet is approximately 180°. In another embodiment, the two magnetshave different magnetic temperature coefficients with opposite signs,and the angle between the direction of magnetization of the first magnetand that of the second magnet is approximately 0°.

[0020] In particular, in accordance with the present invention isprovided an apparatus for generating a temperature-stabilized magneticfield for conducting nuclear magnetic resonance (NMR) measurements, theapparatus comprising: a first magnet that generates a first magneticfield B1 in a test region, wherein the first magnetic field has acomponent B1 z in a direction z, which component increases withincreasing temperature; and a second magnet that generates a secondmagnetic field B2 in the test region, wherein the second magnetic fieldhas a component B2 z in the direction z, which component decreases withincreasing temperature.

[0021] In another aspect, an apparatus for generating atemperature-stabilized magnetic field is provided for conducting NMRmeasurements, the apparatus comprising: a first magnet with a firstmagnetization in a direction z; and a second magnet with a secondmagnetization in the direction −z; wherein the first and second magnetshave magnetic temperature coefficients of the same sign. In analternative embodiment, an apparatus for generating atemperature-stabilized magnetic field is provided for conducting NMRmeasurements, the apparatus comprising: a first magnet with a firstmagnetization in a direction z; and a second magnet with a secondmagnetization in the direction z; wherein the first and second magnetshave magnetic temperature coefficients of opposite signs.

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] The present invention will be understood and appreciated morefully from the following detailed description taken in conjunction withthe drawings in which:

[0023]FIG. 1 is a partially pictorial, partially block diagramillustration of one embodiment of a modular fluid testing apparatus forobtaining nuclear magnetic resonance measurements of fluids near ageologic structure;

[0024]FIGS. 2A through 2D depict one embodiment the steps involved inmeasuring fluids using the modular NMR testing apparatus;

[0025]FIG. 3 is an illustration of the configuration of a permanentmagnet arrangement described in U.S. Pat. No. 6,111,408;

[0026]FIG. 4 illustrates one version of a pulse and echo acquisitionsequence used for NMR fluid measurements;

[0027]FIG. 5 shows one embodiment of a pulse sequence and acorresponding time function of the gradient field used for diffusionmeasurements;

[0028]FIG. 6 is a cross-section of one embodiment of the permanentmagnets and pressure barrel used in accordance with the presentinvention to generate a uniform, temperature compensated magnetic field;

[0029]FIG. 7 is a cross-sectional view showing the flux line computationfor one embodiment of the present invention using a ring magnet withexternal steel ring; and

[0030]FIG. 8 is a cross-sectional view of the ring magnet in FIG. 7showing the effect on the flux lines of removing the steel ring.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0031] Reference is first made to FIG. 6, which illustrates across-section of one arrangement of magnets and a pressure barrel usedin accordance with the present invention to provide atemperature-compensated magnetic field for NMR measurements. Thisarrangement can be used in a sensing system, such as the type shown inFIG. 1 by way of example. FIG. 1 is a partially pictorial, partiallyblock diagram illustration of one embodiment of a modular fluid testingapparatus for NMR analyses and is described in detail in U.S. Pat. No.6,111,408 to the present inventors. The cross-section in FIG. 6, forsimplicity, omits external components, such as the coil windings andshield and illustrates only the magnets, 62 and 66, and the soft-ironvessel 31.

[0032] The magnet configuration described in U.S. Pat. No. 6,111,408 isillustrated further in FIG. 3. It is constructed of samarium-cobaltsegments configured, as shown, as a Halbach magnet. The construction ofsuch magnet configuration is disclosed, for example, in U.S. Pat. No.4,931,760 for use in medical imaging application. As FIG. 3 shows, thismagnet configuration is formed by eight longitudinal segments withvarying directions of magnetization, joined to form an elongatedeight-sided structure. This magnet configuration generally does notprovide temperature compensation, and has no external low-resistancepath for the magnetic flux.

[0033] In a preferred embodiment of this invention, the magnet section16 in FIG. 1, comprises two concentric tubular magnets, as illustratedin FIG. 6 in cross-section. In one embodiment, the direction ofmagnetization of these tubular magnets is uniform around theircircumference, as shown by the arrows in FIG. 6. The length of thepermanent magnet is generally determined by design constraints. It willbe appreciated that this length affects the signal-to-noise ratio (SNR)of the measured signals, with longer magnets generally resulting inimproved SNR.

[0034] In the embodiment illustrated in FIG. 6, segments of permanentmagnet material are arranged around a cylindrical interior volume. Incontrast to the Halbach configuration shown in FIG. 3, all magnetsegments in the sensing system are preferably magnetized insubstantially the same direction. This direction is perpendicular to thelongitudinal axis of the resulting cylinder. The segments are joinedtogether to form a cylinder 62 within which a homogeneous, transversemagnetic field Bo is generated, having a substantially uniform directionz. In accordance with the invention, the number of segments joined isnot critical and is determined by design constraints. In a preferredembodiment, eight segments are joined to form a tube or cylinder.Advantageously, the resulting cylinder could be magnetized afterassembly, which makes the magnet configuration simpler to manufacture.

[0035] It will further be appreciated that the strength of the magneticfield B₀ in the illustrated configuration may be varied for differentdesigns. In a preferred embodiment, a transverse field B₀ ofapproximately 1000 Gauss may be generated by use of eightsamarium-cobalt or other rare-earth material magnet segments, eachmagnetized to about 10,000 Gauss and joined to form a cylinder withinside diameter of 1.59 inches and outside diameter of 1.87 inches.

[0036] In accordance with the invention, a second cylindrical or tubularpermanent magnet 66 is employed to at least partially compensate for thetemperature-dependent properties of the first magnet element 62. In oneembodiment of the sensing apparatus, this second magnet has the samelongitudinal axis as the first magnet. The second magnet may also beconstructed of segments joined to form a tube or cylinder 66. In oneembodiment shown in FIG. 6 this second magnet is enclosed within thefirst magnet. In another embodiment the second magnet may be positionedoutside of the first magnet. This second magnet is made in accordancewith the invention of magnetic material that has a temperaturecoefficient different from that of the first magnet. The segments of thesecond magnet are all magnetized in the same direction, which issubstantially perpendicular to the longitudinal axis of the cylindercomprising the second magnet. The angle between the direction ofmagnetization of the first magnet and the second magnet may vary indifferent embodiments of the apparatus. It will be appreciated that thedegree of temperature-compensation will also vary depending on thisangle. In a preferred embodiment shown in FIG. 6, this angle isapproximately 180 degrees, which maximizes the temperature compensationeffect.

[0037] As indicated above, the first and second magnets may be made of avariety of materials. For example, the materials used may both exhibitnegative magnetic temperature coefficients. However, the temperaturecoefficients of the two materials used must differ in order to producetemperature compensation of the magnetic field B₀. In one embodiment,the first magnet 62 is made of samarium-cobalt (SmCo) alloy and thesecond magnet 66 is made of neodymium-iron-boron (NeFeB). In anotherembodiment the first magnet could be made of NeFeB and the second magnetof SmCo. Other magnetic materials could be used in combination witheither SmCo or NeFeB, for example, barium-ferrite or other rare-earthcomposites.

[0038] The cross-sectional areas of the first magnet 62 and the secondmagnet 66 may vary in different embodiments of the magnetic assembly. Ina preferred embodiment the cross-sections are chosen to have a ratiothat is proportional to the ratio of the inverse of the respectivetemperature coefficients of the material from which the magnets aremade. For example, if one magnet is constructed of samarium-cobalt witha temperature coefficient of −0.03%/K and the other magnet isconstructed of neodymium-iron-boron with a temperature coefficient of−0.12%/K then the ratios of cross-sectional areas in a preferredembodiment would be 4:1. In this ratio, the temperature drifts of thetwo magnets used in accordance with this invention would have thegreatest tendency to cancel each other out.

[0039] It should be noted that the magnetic components and fieldstrength are not limited to the materials and strength mentioned. Othermaterials and design parameters may be employed as appropriate forparticular operational constraints, as would be known to one skilled inthe art of NMR magnet design.

[0040] With reference to FIG. 6, the co-axial first magnet 62 and secondmagnet 66 are surrounded by a tubular pressure barrel 31 that isco-axial with the first and second magnets. This pressure barrel extendsthe length of first and second magnets and is constructed of a materialthat has high relative magnetic permeability, so as to provide a lowresistance return path for the magnetic flux lines outside of themagnets. It will be appreciated that the composition and relativepermeability of the pressure barrel may vary.

[0041] In a preferred embodiment, the barrel is made of low-carbon steelwith a relative permeability of approximately 1000 In one embodiment,the barrel is made with 1018 low-carbon steel. The dimensions of thebarrel are not critical and are determined from design constraints ofthe logging tool housing the NMR tester. In a preferred embodiment, theinside diameter of the barrel 64 is approximately 2.25 inches and theoutside diameter is approximately 3.00 inches. Generally, it is requiredthat the material of which the barrel is made be capable of withstandingthe temperature and pressure conditions in a typical boreholeenvironment. In a preferred embodiment the pressure barrel is able towithstand high internal pressure, so as to provide support for thepressure vessel, shown as element 20 in FIG. 1, which contains the fluidsample to be tested.

[0042] In addition to providing support for the pressure vessel, thepressure barrel can increase the homogeneity and flux density of themagnetic field within the interior of the tubular magnets by providingclose return path for the external magnetic flux. FIG. 7 shows thecalculated flux density for a ring magnet with an external steel ring.FIG. 8 shows the effect of removing the steel ring. Comparing the twofigures shows that without the external return path for the magneticflux lines the flux density inside the ring magnet decreasessubstantially. It will be apparent that the increased flux density andhomogeneity of the internal magnetic field may improve thesignal-to-noise ratio of the NMR measurements made with the magneticfield generating apparatus. In addition, using a pressure barrel inaccordance with this invention is more efficient in the sense that itallows the system to achieve a higher internal flux density for a givenvolume of magnetic material.

[0043] Located within the permanent magnet (shown as 16 in FIG. 1) ispressure vessel 20 having a test chamber therein for holding fluidsamples. As shown in the figure, pressure vessel 20 has a longitudinalaxis 14 that is coaxial with longitudinal axis 18 of the permanentmagnet. Pressure vessel 20 is preferably fabricated of non-conductivematerials such as ceramics, or preferably fiberglass. Generally, it isrequired that the material of which the vessel is made be capable ofwithstanding the temperature and pressure conditions in a typicalborehole environment. The dimensions of the vessel are not critical andare determined from design constraints of the logging tool housing themodular NMR tester. In a preferred embodiment, the inside diameter ofthe vessel 20 is approximately 1 cm and the test chamber isapproximately 15 cm long, so that the vessel is capable of holding asample volume of approximately 10 cm³. Different holding volumes may beused, as required.

[0044] Vessel 20 is adapted to receive and discharge fluids and to thisend is connected by inlet valve 22 and outlet valve 24 to externalpressure tubes (not shown) that form part of the logging tool and aretypically made of steel. Valves 22 and 24 are operated to allow fluidsamples to enter the instrument from one end, preferably from the top inorder to use the force of gravity, hold samples for the duration of theNMR measurements and to discharge samples from the other end aftercompletion of the NMR measurement cycle.

[0045] The external equipment required to supply the borehole fluids tobe tested to the pressure vessel 20 is generally known to one skilled inthe art of downhole well logging. In the simplest case, it comprises apressure probe that is hydraulically activated from within a module thatisolates the borehole pressure from the probe. The probe penetrates themud in the borehole and is inserted into the rock at a desired locationin the sidewall of the borehole. Generally, the invading fluid in theborehole is sealed off, so that preferably only native fluid from therock is pumped into the tester. At least a portion of this fluid ispreferably diverted through valve 22 into the test chamber of the NMRtester described herein. For a more detailed description of the externalequipment the reader is directed to the product literature concerningthe commercially available logging tools, such as those manufactured byHalliburton, Schlumberger and Western Atlas.

[0046] In alternative embodiments (not shown) vessel 20 need not beclosed as illustrated in FIG. 1, so that one or both of valves 22 and 24may be eliminated. Thus, in a specific embodiment vessel 20 is merely aportion of a duct in which fluid to be tested may flow continuously. Insuch case, measurements are taken on the volume of fluid surrounded bythe permanent magnet at the time of the NMR experiment (the testvolume). In an alternative embodiment, vessel 20 only has one closed endillustrated in FIG. 1, for example, by valve 24. In this case, the flowof the fluid may be interrupted during measurements by closing off valve24, and may resume by opening the valve on command by a computer 42. Ineach case, provisions may be made to expel fluids from the test volumeby various means, as known in the art. Finally, control of the fluidflow may be implemented using the external equipment. It should thus beunderstood that the vessel 20 may be either a closed container or a ductor an arrangement that enables controlled flow of fluid through thevolume surrounded by the permanent magnet.

[0047] Test portion 10 of the testing apparatus also preferablycomprises one or more coil windings 26 that are arranged around vessel20. Since it is important to have the coil windings 26 as close to thefluid sample as possible for the NMR measurements performed using thisdevice, in a preferred embodiment windings 26 are embedded in the wallsof pressure vessel 20. In operation, coil 26 generates a magnetic fieldB₁ (not shown) to excite nuclear magnetic relaxation in the test fluidand then receives NMR signals from the fluid samples contained withinvessel 20. The magnetic field B₁ is polarized in a direction parallel tothe longitudinal axis 18 of the permanent magnet 16, and thus isperpendicular to the direction of the magnetic field B₀. In a preferredembodiment, the B₁ field is operated at a frequency that may be variedin accordance with the strength of the B₀ field. As known in the art,the required operating frequency of the magnetic field is given by theexpression F₁=42,580 Hz/mT×B₀, where 42,580 Hz/mT is the gyromagneticratio for hydrogen NMR. In a specific illustrative embodiment where Bois 47 milli Tesla (mT), B₁ is operated at approximately 2 MHZ. It shouldbe noted that in a preferred embodiment the matching and tuning circuitfor the coil 26 enable single-tuning, i.e., for hydrogen frequency only,or multiple-tuning for NMR measurements of additional elements, such asthe “³C isotope. This feature is based on the fact that a given magneticfield requires different operating frequencies for different atomicisotopes.

[0048] With reference to FIG. 1, the return path of the coil current isprovided through a copper shield 28 that separates the interior, radiofrequency section of test portion 10 from the permanent magnet.Accordingly, the magnetic field lines of B₁ do not penetrate thepermanent magnet and cannot excite undesirable magneto-acousticoscillations.

[0049] In the embodiment illustrated in FIG. 1, one or more magneticfield gradient coils 30 are located between coil windings 26 and coppershield 28 to generate a magnetic field gradient. The gradient coil 30 isessential for performing rapid, high-SNR self diffusion measurements. Ina preferred embodiment, coil 30 is of a saddle type with two separateloops generating fields in the x direction. In a preferred embodiment,saddle coil 30 is driven as a Maxwell pair such that the gradient fieldenhances the uniform field B₀ in the positive x direction and opposes itin the negative x direction, thereby creating a steerable field gradientdb₀/dx.

[0050] The coil windings 26, together with a (T/R) matching circuit 34shown in FIG. 1 define a transmitter/receiver (T/R) circuit required forthe NMR measurements. T/R matching circuit 34 typically includes aresonance capacitor, a T/R switch and both to-transmitter andto-receiver matching circuitry. Circuit 34 is coupled to a first RFpower amplifier 35 and optionally to a second RF amplifier 36 and to areceiver preamplifier 37. A relay outlet 38 is linked to valves 22 and24. A power supply 39 provides the dc current required for the magneticfield gradient generating coil(s) 30.

[0051] The coil 26 shown in FIG. 1 is of a solenoid type. In analternative embodiment (not shown), coil 26 may be of a saddle type. Inthis case, with reference to FIG. 1, some of the windings of the coilwould face away from the drawing sheet as to generate a magnetic fieldwith the appropriate direction.

[0052] In another embodiment of the antenna (not shown), two separatecoils are used—one as a transmitter and the other as a receiver antenna.In such a case, one of the coils is preferably of a solenoid type (asshown in FIG. 1) whereas the other is preferably of a saddle type. Thesolenoid type coil is preferably used as a receiving antenna and ispreferably embedded in the walls of the vessel as to increase itssensitivity. The saddle type coil is used in this case as a transmitter,and is located further away from the axis of the vessel compared withthe receiver. Alternatively, the saddle type coil may be used a receiverand the solenoid coil as a transmitter. An advantage of having twoantennae is that in such case there is no need for a T/R matchingcircuit 34, so that the transmitter antenna may be connected directly toRF amplifier 35, whereas the receiver antenna may be connected directlyto preamplifier 37.

[0053] The calibration of the testing apparatus is preferablyaccomplished using calibration fluid. As shown in a specific embodimentin FIG. 1, a reservoir tank 33 holding calibration fluid, such asdistilled water, may be located proximate the pressure barrel 31. In apreferred embodiment, the water may be doped with cupric sulfate tolower the NMR relaxation times to approximately 200 milliseconds atreservoir temperatures. The vessel 20 may be filled with approximately10 cm³ fluid at a time from the reservoir tank 33. Since the hydrogencontent and the self-diffusion coefficient of distilled water as afunction of temperature are known, measurements on the water sampleserve as tool calibrations under actual temperature and pressureconditions. The artificially lowered relaxation times, T₁ and T₂, permitrapid pulsing and therefore fast acquisition of NMR signals. Temperaturemeasurements are preferably made using a transducer 21, as shown inFIG. 1. In alternative embodiments of the operation, calibration fluidis used to fill the vessel 20 prior to lowering the device in theborehole, so that there is no need for a separate reservoir tank.

[0054] In a specific embodiment, all of the elements described above arecontained in a housing 40, which in operation forms part, i.e., anadd-on, of a larger logging tool and is passed along with the toolthrough the borehole. In alternative embodiments some of the elementsillustrated in FIG. 1 as part of the housing 40 may be located aboveground.

[0055] Block 41 in FIG. 1 is a block diagram of one embodiment of thecontrol circuitry for the downhole NMR tester. As shown, the controlcircuitry may comprise a computer 48 that provides a control output to apulse programmer 44. Pulse programmer 44 is responsible for generatingNMR pulse sequences of predetermined frequency, phase shift andduration. To this end, pulse programmer 44 controls the operation of avariable frequency RF source 46 and phase shifter 52, as well as an RFpre-amplifier 48. The pulsed RF output of pre-amplifier 42 which has theappropriate frequency and phase shift is supplied to RF power amplifier35 and optionally to RF amplifier 36. The output of amplifier 35 (and/or36) is finally passed through T/R matching circuit 34 to coil 26, whichgenerates the magnetic field B₁ to excite nuclei in the fluid beingtested.

[0056] NMR echo signals generated from the excited nuclei in the fluidcontained in the test chamber are picked up by the coil 26 and passedthrough the T/R matching circuit 34 to receiver pre-amplifier 37. Theoutput of RF receiver preamplifier 37 is supplied to an RF receiver 50,which preferably also receives an input from phase shifter 52. Theoutput of receiver 50 is provided via an A/D converter with a buffer 54to computer 42 for further processing and analysis of the NMR echosignals. Pulse programmer 56 controls the gradient coil power supply 39controlling the current flow, and hence the generation of fieldgradients, according to the commands of the computer 42.

[0057] Control circuits for generating pulse sequences havingpredetermined parameters and for measuring NMR echo signals from testmaterials and their operation are generally known in the art and neednot be described in detail. Therefore, it should be understood that theconfiguration shown in FIG. 1 is only illustrative and may be varied inalternative embodiments of the control system.

[0058] Reference is now made to FIGS. 2A through 2D, which illustratecertain steps involved in a specific embodiment for measuring fluidsusing the modular tester. Thus, in FIG. 2A, both valves are open andwater is flushed through the test chamber of the pressure vessel 20 inpreparation for the testing of fluids. Thereafter, both valves areclosed and as shown in FIG. 2B, calibration fluid, such as distilledwater, is sent to fill vessel 20 for NMR testing and recordation. NMRtesting is performed on the calibration fluid in order to provide apoint of reference for subsequent fluids to be tested. It will beappreciated that reference points obtained in this measurement arestored in a memory of computer 42. FIG. 2C illustrates the step ofdischarging the calibration fluid through the open lower valve after thecalibration measurements have been taken. At this point, the apparatusis ready for testing of fluids within the borehole. FIG. 2D represents asample fluid being taken through the open upper valve into vessel 20 fortesting. Depending on the geometry of vessel 20 and the viscosity of thevarious fluids, one or both valves may be opened during the proceduresof FIGS. 2C and 2D.

[0059] The method is preferably practiced using a two-pass technique.Thus, in a preferred embodiment, the first pass through the borehole maybe performed using, for example, the MRIL® tool described above toobtain a fast log providing an indication of the petrophysicalproperties of the rock in the vicinity of the borehole. Following thisstage, the complete log of the rock formation along the borehole may beused to identify target zones of interest for performing directmeasurements. The measurements made in the first pass are well known inthe art and need not be described in detail. The reader is directed tothe disclosures of U.S. Pat. Nos. 4,710,713; 4,717,876; 4,717,877;4,717,878; 5,212,447; 5,280,243; 5,309,098; 5,412,320; 5,517,115;5,557,200; 5,696,448; 5,936,405; 6,005,389; 6,023,164; 6,051,973;6,107,796 and 6,111,408 all of which are commonly owned by the assigneeof the present application. Additional information is provided in U.S.Pat. Nos. 5,055,787 and 5,055,788. The content of the above patents ishereby incorporated by reference for all purposes.

[0060] Once the target zones have been identified, a second pass ispreferably made using any one of the commercial downhole testersdescribed above. Second pass measurements are typically made only in thetarget zones as a cost saving measure. The direct downhole NMRmeasurements using the modular tester are then performed as describedbelow. Finally, the results of the NMR measurements are interpreteddirectly, and/or used to provide more accurate interpretation of the logobtained in the first pass.

[0061] In an alternative embodiment, provisions may be made for usingthe modular NMR tester to perform measurements during the drilling ofthe borehole, or as part of the first pass described above.

[0062] The downhole NMR tester is preferably used to providemeasurements of one or more of the following parameters of the fluidsamples: (a) hydrogen density, i.e., the number of hydrogen atoms perunit volume; (b) self-diffusivity (which is inversely related to thefluid viscosity); and (c) nuclear relaxation times T₁ and T₂ fordifferent operating frequencies depending on the atomic elements ofinterest. Additional measurements may be made using the multiple-tuningcapability of the tester for estimating, for example, carbon density,hydrogen-carbon coupling and/or obtaining polarization transferinformation, and others.

[0063] In one embodiment of the operation of the NMR sensing system, thedetermination of the hydrogen index and the T₁ and T₂ relaxation timesis based on CPMG pulse-echo trains having an echo spacing ofapproximately 0.5 milliseconds (ms) as shown in FIG. 4. Approximately10,000 pulse signals may be generated and the corresponding echo signalsmay be digitized, stored and accumulated in a specific embodiment. Themethods for parameter derivation using such NMR measurements are knownin the art and need not be discussed in detail. In the specificapplication, however, it is necessary to determine certain operatingparameters of the system.

[0064] For example, the echo acquisition time in a preferred embodimentis approximately 0.1 ms. Other times may also be used, if desired.Assuming an echo acquisition time of 0.1 ms, the maximum tolerable fielddistortion is then determined using the condition T₂*>0.1 ms, where T₂*is a time constant that characterizes the apparent NMR signal decay. Bysetting a lower limit for T₂* of 0.1 milliseconds, r.m.s. fielddistortions equivalent to 10 kHz or 0.5% of the main B₀ field areallowed.

[0065] It is important to realize that relaxation times of bulk fluidscan be as high as 10 sec in reservoir conditions. To achieve an error ofless than about 1% of the hydrogen index, measurements must be spacedout to about five times the relaxation times, i.e., to about 50 sec.Therefore, it would clearly be impractical to perform a large number ofindividual measurements in order to increase the signal SNR and only afew measurements must suffice to achieve the required signal SNR. Inthis regard, it is worth emphasizing that the SNR of the measuredsignals may be varied simply by changing the measurement volume of fluidin the test chamber. As noted above, this may be accomplished in thetester by expanding the chamber along its longitudinal axis, andcorrespondingly increasing the length of the permanent magnet. It hasbeen estimated that for the illustrative embodiment discussed abovewherein the test chamber contains 10 cm³ of fluid, the singlemeasurement SNR is approximately about 100:1.

[0066] The wait time between CPMG pulse-echo trains is preferablydetermined both by the longest T₁ measurements and by the requirementsof the T₁ measurements. In a preferred embodiment, the wait times usedby the tester may be set to 0.01. 0.03, 0.1, 0.3, 1.0, 3.0, 10.0 and50.0 seconds, as shown in FIG. 4. Other wait time sequences may be used,if desired.

[0067] As known in the art, the hydrogen index of the fluid sample isdetermined by extrapolating the echo amplitudes from at least onephase-alternated CPMG pair to time equal to 0 (π/2 pulse). The ratio ofthis amplitude, compared to the amplitude given by the water reference,equals the relative hydrogen content of the sample fluid. It can beappreciated that by using the multi-tuning capability of the tester,additional measurements may be made for the presence of other atomicelements, such as ¹³C.

[0068] The T₂ relaxation parameter is determined in one embodiment ofthe operating procedure by transforming the time-domain echo data into aT₂ time distribution. The T₁ relaxation time is preferably determined byobserving the effect of different wait times on the time equal to 0 (π/2pulse) amplitude. The resultant recovery curve may be transformed into aT₁ time distribution, according to calculations known in the art.

[0069] The downhole NMR tester may further be used to providediffusivity and viscosity measurements. Referring to FIG. 5, a fieldgradient is used in a preferred embodiment to perform thesemeasurements. In particular, the field is used to overcome thebackground field variations using the following steps.

[0070] As shown in FIG. 5, a standard CPMG sequence is used with an echospacing of about 0.5 milliseconds. This short echo spacing greatlyattenuates the effects of the gradients arising from an imperfectmagnetic field B₀. The actual echo spacing may be varied within somelimits. In the beginning of the CPMG train, the gradient is turned onwith a frequency corresponding to the selected echo spacing time for afew cycles. In the specific embodiment using 0.5 ms echo spacing, agradient frequency of 1 kHz is used. The amplitude of the gradient fieldis relatively small compared with the static field and in a preferredembodiment is between a fraction of 1% to about a few percent of thestrength of the Bo field. As shown in FIG. 5, the gradient isphase-locked such that its zero-crossings coincide with the pulses beingapplied. This period is the phase-encoding stage. Next, the gradient isturned off for an evolution time of about 10 to 1000 ms. In a preferredembodiment, about 100 milliseconds evolution time is used during whichtime the hydrogen spins are free to diffuse within the measurementvolume. After the evolution time, the gradient is turned on again at theselect frequency, i.e., 1 kHz, but in a phase that undoes the effect ofthe phase-encoding stage. After this phase-decoding operation, CPMGechoes are acquired in the usual manner.

[0071] It can be appreciated that in the absence of diffusion(corresponding to high viscosity), the final signal is unaffected. Underdiffusion, however, the signal attenuation is directly related to therate of diffusion during the evolution time interval. Accordingly, themeasurements of the downhole NMR tester may be used to estimate theself-diffusivity and thus the viscosity of the fluid directly.

[0072] In essence, the phase-encoding stage translates the position ofthe spins into a phase relationship. The phase-decoding stage does thesame translation with a negative sign. If there has been a net change inthe spin position between the encoding and the decoding stages, theresult of applying the two stages will be a net change in the phaserelationships that would lead to a reduction of the measured signalamplitude. Accordingly, it can be appreciated that the differencebetween measurements of the formation fluid with and without theencoding/decoding processing stages may be used to quantify diffusion inthe fluid.

[0073] The time delay between the phase-encoding and the phase-decodingstages can preferably be varied in some systematic fashion, i.e., 10,100 and 1000 ms, and changes in the signal amplitudes obtained in eachmeasurement may be used to determine the self-diffusion coefficient ofthe fluid, as known in the art. In accordance with another embodiment ofthe operating procedure, a single strong pulse may be used in theencoding stage and another strong pulse with reverse polarity may beused in the decoding stage of the method.

[0074] It will be appreciated by those skilled in the art that thedownhole NMR tester and the parameter measurements may be used in anumber of different ways. For example, as noted above, the measurementsmay be used to enhance the interpretation of previously conducted logmeasurements of the borehole by supplying, essentially in real time,true values for connate oil and drilling mud filtrates under reservoir,i.e., raw conditions.

[0075] Further, those familiar with the operation of the commercialtester tools will appreciate that measurements may be extended in time,so as to provide a record of the fluid passing through the tester over apredetermined period. For example, as known, the sample probes insertedinto the rock may pump fluid out of the rock for periods of about 5-10minutes to 40 hours in some cases. Assuming that a single downhole NMRmeasurement takes about 1 minute to complete, in one hour the tester canprovide 60 independent measurements that are immediately available tothe operator. By contrast, a single prior art NMR measurement of asample taken to the surface may take days to complete. It will beappreciated that to preserve the accuracy of the measurement the testchamber of the vessel 20 may be flushed between measurements, as shownin FIG. 2A. Re-calibration of the tool may be performed in accordancewith a pre-determined schedule, for example every two hours.

[0076] Although the present invention has been described in connectionwith the preferred embodiments, it is not intended to be limited to thespecific form set forth herein, but on the contrary, it is intended tocover such modifications, alternatives, and equivalents as may bereasonably included within the spirit and scope of the invention asdefined by the following claims.

What is claimed is:
 1. An apparatus for generating atemperature-stabilized magnetic field for conducting nuclear magneticresonance (NMR) measurements, the apparatus comprising: a first magnetthat generates a first magnetic field B1 in a test region, wherein thefirst magnetic field has a component B1 z in a direction z, whichcomponent varies with temperature according to a first relationship; anda second magnet that generates a second magnetic field B2 in the testregion, wherein the second magnetic field has a component B2 z in thedirection z, which component varies with temperature according to asecond relationship, different from the first relationship over atemperature range of interest.
 2. The apparatus of claim 1, wherein thefirst magnet is a tubular magnet.
 3. The apparatus of claim 1, whereinthe first and second magnets have geometries and magnetizations suchthat over a predetermined temperature range the temperature variation ofB1 z is substantially equal in magnitude but opposite the temperaturevariation of B2 z.
 4. The apparatus of claim 3, wherein the temperaturerange of interest is between about 0° C. and 175° C.
 5. The apparatus ofclaim 3, wherein the temperature range of interest includes the range100° C. to 150° C.
 6. The apparatus of claim 1, further comprising atubular pressure barrel disposed around the first and second magnets. 7.The apparatus of claim 6, wherein the tubular pressure barrel comprisesmetal with a high relative magnetic permeability.
 8. The apparatus ofclaim 6, wherein the tubular pressure barrel comprises 1018 low-carbonsteel.
 9. The apparatus of claim 1 wherein the magnetization directionof the first magnet is oriented approximately 180° from themagnetization direction of the second magnet.
 10. The apparatus of claim1 wherein the magnetization direction of the first magnet is orientedapproximately 0° from the magnetization direction of the second magnet.11. The apparatus of claim 1 wherein the first and second magnetsgenerate a combined magnetic field in the test region with a strengthbetween 100 and 10,000 Gauss.
 12. The apparatus of claim 1 wherein thefirst and second magnets generate a combined magnetic field in the testregion with a strength of approximately 1000 Gauss.
 13. The apparatus ofclaim 1 wherein the first magnet comprises a samarium-cobalt alloy andthe second magnet comprises a neodymium-iron-boron alloy.
 14. Anapparatus for generating a temperature-stabilized magnetic field forconducting nuclear magnetic resonance (NMR) measurements, the apparatuscomprising: a first magnet with a first magnetization in a direction z;and a second magnet with a second magnetization in the direction −z;wherein the first and second magnets have magnetic temperaturecoefficients of the same sign to produce a temperature-stabilizedmagnetic field in an area of interest.
 15. The apparatus of claim 14,wherein the magnetic temperature coefficients of the first and secondmagnets have a negative sign.
 16. The apparatus of claim 14, wherein thefirst magnet is a tubular magnet.
 17. The apparatus of claim 16, whereinthe second magnet is concentrically disposed tubular magnet enclosingthe first magnet.
 18. The apparatus of claim 17, wherein the directionof magnetization of the first and second magnets is uniform around theircircumference.
 19. The apparatus of claim 14, wherein the length of thefirst and second magnets is determined by design constraints, saidconstraints comprising the signal-to-noise ratio (SNR) of the measuredsignals.
 20. The apparatus of claim 14, wherein the first and secondmagnets comprise segments of permanent magnet material arranged around asubstantially cylindrical interior volume.
 21. The apparatus of claim20, wherein all magnet segments of the first magnet are magnetized in adirection z; and all magnet segments of the second magnet are magnetizedin a direction −z.
 22. The apparatus of claim 20, wherein the magneticfield B₀ in the interior volume is substantially homogeneous, having asubstantially uniform direction z. 23 The apparatus of claim 22, whereinthe magnetic field B₀ in the interior volume is temperature-stabilizedover a range of about 0° C. to 175° C.
 24. The apparatus of claim 14further comprising a tubular pressure barrel disposed around the firstand second magnets.
 25. The apparatus of claim 14, wherein the first andsecond magnets generate a combined magnetic field in the test regionwith a strength between 100 and 10,000 Gauss.
 26. The apparatus of claim14, wherein the first magnet comprises a samarium-cobalt alloy and thesecond magnet comprises a neodymium-iron-boron alloy.
 27. An apparatusfor generating a temperature-stabilized magnetic field for conductingnuclear magnetic resonance (NMR) measurements, the apparatus comprising:a first magnet with a first magnetization in a direction z; and a secondmagnet with a second magnetization in the direction z; wherein the firstand second magnets have magnetic temperature coefficients of oppositesigns.